1. Phenylpyrazole
2. Systemic, broad-spectrum insecticide
3. Contact, ingestion action
4. Effective against adult and larval stage
5. 80%WG, 20%FS

Chemical Identification

Common Name:	Fipronil
IUPAC Name:	(±)-5-amino-1-(2,6-dichloro-α,α,α-trifluoro-p-tolyl)-4-trifluoromethylsulfinylpyrazole-3 -carbonitrile
CAS Name:	5-amino-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(1R,S)-(trifluoromethyl)sulfinyl]-1H -pyrazole-3-carbonitrile
CAS No.:	120068-37-3
EINECS No.:	424-610-5
Form for TC:	White powder
Melting Point:	200-201 °C; (tech., 195.5-203 °C)
Density:	1.477-1.626 (20 °C)
Solubility:	In water 1.9 (pH 5), 2.4 (pH 9), 1.9 (distilled) (all in mg/l, 20 °C).
Stability:	Stable in water at pH 5 and 7; slowly hydrolysed at pH 9. Stable to heat. Slowly  degrades in sunlight.
Molecular Weight:	437.2
Molecular Formula:	C12H4Cl2F6N4OS
Molecular Structure:

Other Brand Names:

• Adonis, Agenda, Ascend, Blitz, Chipco Choice, Cosmos, Fipridor, Fiprosun, Frontline, Gard, Garnet, Goliath, Icon, Maxforce, Metis, Prince, Regent, Termidor, Texas, Top Choice, Vi-nil, Violin, etc.

• Amistar-Prince (Fipronil + Azoxystrobin), ArashiPrince (Fipronil + Orysastrobin), Builder Prince (Fipronil + Probenazole), Delaus-Prince (Fipronil + Diclocymet), Dr. Oryze-Prince (Fipronil + Probenazole, Fuji-one Prince (Fipronil + Isoprothiolane), Gazette Prince (Fipronil + Carbosulfan), Jumper (Fipronil + Guazatine Acetates + Triticonazole), Pika Pika (Fipronil + Isoprothiolane + Pyroquilon), V-Get Prince (Fipronil + Tiadinil), Zoom (Fipronil + Guazatine Acetates + Triticonazole), etc.

Product Information

General Formulations:

• Fipronil 97% TC

• Fipronil 200g/L (2.5%, 5%, 10%, 25%, 50%) SC

• Fipronil 3% GR

• Fipronil 50g/L FS

• Fipronil 70% WP

• Fipronil 80% WDG

• Fipronil 80% DF

Mixture Formulations:

• Fipronil + Abamectin + Phoxim + Chlorpyrifos 4%+1%+16%+10% EC

• Fipronil + Abamectin 1g/L+35g/L EC

• Fipronil + Abamectin 50g/L+5g/L SC

• Fipronil + Acetamiprid 49.8g/L+0.9g/L FS

• Fipronil + Acetamiprid 5%+3% EC

• Fipronil + Buprofezin 5%+25% WP

• Fipronil + Cartap hydrochloride 2.5%+47.5% WP

• Fipronil + Chlorfluazuron 16%+10% EC

• Fipronil + Chlorfluazuron 32%+20% WP

• Fipronil + Chlorpyrifos 10g/L+150g/L EC

• Fipronil + Deltamethrin 2.5% +1.0% EC

• Fipronil + Difenoconazole 25%+25% WDG

• Fipronil + Difenoconazole 250g/L+250g/L SC

• Fipronil + Emamectin Benzoate 15%+5% WDG

• Fipronil + Fenobucarb 2%+16% EC

• Fipronil + Hexaflumuron 10%+10% SC

• Fipronil + Imidacloprid + Pyridaben 5%+10%+30% SC

• Fipronil + Imidacloprid 25%+25% SC

• Fipronil + Imidacloprid 60%+15% WG (80%+3%)

• Fipronil + Lambda-cyhalothrin 20%+10% SC

• Fipronil + Lambda-cyhalothrin 3.5%+1.5% EC (5%+5%)

• Fipronil + Matrine 5%+1.3% SC

• Fipronil + Metalaxyl + Fludioxonil 6%+1%+2.5% FS

• Fipronil + Nitenpyram 26%+54% WP

• Fipronil + Pymetrozine 8.5%+50% WDG

• Fipronil + Quinalphos 2.5%+22.5% EC

• Fipronil + Thiacloprid + Thiamethoxam 10%+55%+10.7% WP

• Fipronil + Thiamethoxam 0.5%+29.5% WG

• Fipronil + Thiamethoxam 10%+10% WP

• Fipronil + Trichlorfon 1.5%+48.5% EC

• Fipronil + Tricyclazole 1.5%+15% SC

Specifications:

• Spefications of Fipronil 97% TC

Product name: Fipronil 97% TC Manufacturer: Ningbo Titan Unichem Co., Ltd.
TEST ITEMS	SPECIFICATIONS
Appearance	White powder
Content of a.i.	97.0% min
Loss on drying	0.5% max
pH value	4.5-7.5
Insoluble in Acetone	0.5% max

• Specifications of Fipronil 80% WG

Product name: Fipronil 80% WG Manufacturer: Ningbo Titan Unichem Co., Ltd.
TEST ITEMS	SPECIFICATIONS
Appearance	Lighe yellow (Brown) granule
Content of A.I.	80.0% min
Suspensibility	80% min
Dispersion	90% min
pH value	5.0-8.0
Moisture	2.0% max
Wetting time	60s max
Persistent foam (after 1   min)	25ml max
Fineness (pass 44um wet   sieve)	98% min

• Specifications of Fipronil 20% SC

Product name: Fipronil 200g/l SC Manufacturer: Ningbo Titan Unichem Co., Ltd.
TEST ITEMS	SPECIFICATIONS
Appearance	Milky white (Red) liquid
Content of A.I. (w/v)	200g/L min
Suspensibility	85% min
pH value	5.0-8.0
Persistent foam (after 1min)	25ml max
Fineness (pass 44um sieve)	98% min
Heat storage stability	Qualified

• Specifications of Fipronil 5% EC

Product name: Fipronil 50g/L EC Manufacturer: Ningbo Titan Unichem Co., Ltd.
TEST ITEMS	SPECIFICATIONS
Appearance	Light yellow liquid
Content of A.I. (w/v)	50g/L min
Moisture	0.5% max
pH value	5.0-8.0
Emulsion stability	Qualified
Low temperature stability	Qualified
Heat storage stability	Qualified

Pictures:

 

Fipronil 80% WDG (Off-white vs Light-brown) from NINGBO TITAN UNICHEM.

 

Fipronil 80% WDG (Red vs Brown) from NINGBO TITAN UNICHEM.

 

Fipronil 200g/L SC (Red vs White) from NINGBO TITAN UNICHEM.

Packaging:

• For solid product: 10gr ~ 25kg with sachet, aluminum foil bag, bottle, fiber can, jumbo bag, etc;

• For liquid product: 10ml ~ 200Lt, with ampoule/HDPE/CO-EX bottle, bag, drum, IBC, etc;

• Or package as per customer's request for design, material and size.

Delivery Lead Time:

• Within 2 ~ 3 weeks after order confirmation.

Transportation:

• Signal Word: WARNING; Hazard Class: II (Moderately hazardous)

Toxicity Class:

• WHO (a.i.) II; EPA (formulation) II

• Acute oral LD50 for rats 97, mice 95 mg/kg.

Application

Mode of Action:

• Fipronil is an systemic insecticide which acts as a blocker of the GABA-regulated chloride channel.

• Insects resistant or tolerant to pyrethroid, cyclodiene, organophosphorus and/or carbamate insecticides are susceptible to fipronil.

• Fipronil is broad-spectrum insecticide, toxic by contact and ingestion, which is effective against adult and larval stages.

• Fipronil has limited xylem systemicity in some monocotyledonous crops.

• Fipronil can be used to control insects when applied as a soil or seed treatment.

• Fipronil is good to excellent residual control following foliar application.

Usage of Fipronil:

• Fipronil controls multiple species of thrips on a broad range of crops by foliar, soil or seed treatment.

• Fipronil controls corn rootworm, wireworms and termites by soil treatment in maize.

• Fipronil controls boll weevils and plant bugs on cotton, diamond-back moths on crucifers, and Colorado potato beetle on potatoes, by foliar application.

• Fipronil controls stem borers, leaf miners, planthoppers, leaf folders/rollers and weevils in rice.

• Foliar application rates range from 10-80 g/ha; soil treatment rates 100-200 g/ha.

CropUses:

• alfalfa, aubergines, bananas, beans, brassicas, cabbages, cauliflowers, chillies, crucifers, cucurbits, citrus, coffee, cotton, crucifers, garlic, maize, mangos, mangosteens, melons, oilseed rape, onions, ornamentals, peas, peanuts, potatoes, rangeland, rice, soybeans, sugar beet, sugar cane, sunflowers, sweet potatoes, tobacco, tomatoes, turf, watermelons, etc.